What is the meaning of Phase rule?

A generalization with regard to systems of chemical equilibrium, discovered by Prof. J. Willard Gibbs. It may be stated thus: The degree of variableness (number of degrees of freedom) of a system is equal to the number of components minus the number of phases, plus two. Thus, if the components be salt and water, and the phases salt, ice, saturated solution, and vapor, the system is invariant, that is, there is only one set of conditions under which these four phases can exist in equilibrium. If only three phases be considered, the system is univariant, that is, the fixing of one condition, as temperature, determines the others.
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APAWebster's. (2011). phase rule. Retrieved September 27, 2026, from http://smartdefine.org/phase_rule/definitions/2044616
ChicagoWebster's. 2011. "phase rule" http://smartdefine.org/phase_rule/definitions/2044616 (accessed September 27, 2026).
HarvardWebster's 2011, phase rule, Smart Define, viewed 27 September, 2026, <http://smartdefine.org/phase_rule/definitions/2044616>.
MLAWebster's. "phase rule" 27 May 2011. Web. 27 September 2026. <http://smartdefine.org/phase_rule/definitions/2044616>